If you are looking for some self study materials for the new System Center 2012 suite then have a look at these links.
· System Center 2012 Self-Study Guide (Part 1 – System Center Overview)
· System Center 2012 Self-Study Guide (Part 2 – Advisor and App Controller)
· System Center 2012 Self-Study Guide (Part 3 – System Center Configuration Manager)
· System Center 2012 Self-Study Guide (Part 4 – Data Protection Manager and Endpoint Protection)
· System Center 2012 Self-Study Guide (Part 5 – Operations Manager)
· System Center 2012 Self-Study Guide (Part 6 – Orchestrator and Service Manager)
· System Center 2012 Self-Study Guide (Part 7 – Unified Installer and Virtual Machine Manager)
These links were provided by Fabrice at the MS Blogs.